High rate recharge of stationary VRLA batteries

Citation
P. Haring et H. Giess, High rate recharge of stationary VRLA batteries, J POWER SOU, 95(1-2), 2001, pp. 153-161
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics","Environmental Engineering & Energy
Journal title
JOURNAL OF POWER SOURCES
ISSN journal
03787753 → ACNP
Volume
95
Issue
1-2
Year of publication
2001
Pages
153 - 161
Database
ISI
SICI code
0378-7753(20010315)95:1-2<153:HRROSV>2.0.ZU;2-O
Abstract
The high rate charge behavior of 6 V 155 A h lead acid monoblocs of the VRL A type for stationary service, subsequent to a full discharge in 1 h to 1.6 0 Vpc, is described. Charging rates with an initial constant current equal to I-10, 3I(10), 7I(10) and with constant voltage of 2.25 Vpc, resulting in a peak current of 22I(10), were evaluated for their influence on the sites and magnitude of internal heating, speed of recharge and gas emission phen omena. The results indicate that recharge with an initial current in the 3I (10) to 7I(10) range and the maximum voltage limited to 2.25 Vpe appears to be a viable charging strategy. Full recharge can be achieved in 4-6 h with the temperature rise limited to 12 degreesC above ambient and the gas evol ution to an equivalent of 0.41 per cell of a hydrogen-33% oxygen mixture. T he thermal video imaging revealed that the loci of maximum internal heating reflect the IR drop and the heat loss through top lead and monobloc walls. (C) 2001 Elsevier Science B.V. All rights reserved.