Separation of arsenic from germanium oxide targets by dry distillation

Citation
V. Tolmachev et H. Lundqvist, Separation of arsenic from germanium oxide targets by dry distillation, J RAD NUCL, 247(1), 2001, pp. 61-66
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
247
Issue
1
Year of publication
2001
Pages
61 - 66
Database
ISI
SICI code
0236-5731(200101)247:1<61:SOAFGO>2.0.ZU;2-V
Abstract
Positron-emitting isotopes of arsenic, As-70 (T-1/2 = 53 min), As-71 (T-1/2 = 64 h), (72)AS (T-1/2 = 26 h), and As-73 (T-1/2 = 17.8 d) are of interest in biomedical investigations using PET. A fast and simple method for their production using low-energy proton and deuteron reactions on enriched Ge-t argets is presented. Dry distillation of GeO2 at 1105 degreesC during 2 hou rs provides a separation efficiency of more than 60%. The loss of target ma terial is less than one per cent and the irradiated targets can be used sev eral times. The method allows production of diagnostically useful amounts o f positron-emitting arsenic isotopes using accelerators commonly available at PET-centres.