Investigation of property of silver complex solution with p-iodobenzenediazoaminoazobenzene by spectral correction technique

Authors
Gao, HW Meng, P Wang, L
Citation
Hw. Gao et al., Investigation of property of silver complex solution with p-iodobenzenediazoaminoazobenzene by spectral correction technique, J INDIAN CH, 78(1), 2001, pp. 9-12
Citations number
12
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF THE INDIAN CHEMICAL SOCIETY
ISSN journal
00194522 → ACNP
Volume
78
Issue
1
Year of publication
2001
Pages
9 - 12
Database
ISI
SICI code
0019-4522(200101)78:1<9:IOPOSC>2.0.ZU;2-A
Abstract
Complexation between silver (Ag+) and p-iodobenzenediazoaminoazobenzene (p- IBDA) has been investigated in alkaline solution. The surfactants, polyoxye thylene alcohol (OP) and sodium dodecyl benzene sulfonate (SDBS) have been used because their micelles can improve the dissolution of the Ag-p-IBDA co mplex and increase the reaction sensitivity. Its true (not apparent) molar absorptivity is epsilon (480)(Ag(p-IBDA)) = 3.42 x 10(4) in OP solution and epsilon (490)(Ag(p-IBDA)) = 2.59 x 10(4) dm(3) mol(-1) cm(-1) in SDBS solu tion. The stability constants of the complex are 1.63 x 10(7) and 5.16 x 10 (4) in OP and SDBS solutions, respectively.