Surface-confined monomers on electrode surfaces. 10. Electrochemical and infrared spectroscopic characteristics of aniline-terminated alkanethiol monolayers on Au electrochemically treated in aqueous solution
Rc. Schomburg et Rl. Mccarley, Surface-confined monomers on electrode surfaces. 10. Electrochemical and infrared spectroscopic characteristics of aniline-terminated alkanethiol monolayers on Au electrochemically treated in aqueous solution, LANGMUIR, 17(6), 2001, pp. 1983-1992
We have synthesized and conducted studies on two self-assembled monolayers
which have an oxyaniline tail group that is tethered to a gold surface via
an alkanethiol chain. Reflection-absorption infrared spectroscopy (RAIRS),
electrochemical, and contact angle measurements were performed on pristine
2-(6-mercaptohexan-1-oxy)aniline (AnC6SH) and 2-(7-mercaptoheptan-1-oxy)ani
line (AnC7SH) monolayers on planar Au surfaces. The pristine monolayers wer
e electrochemically oxidized in 1 M H2SO4, and the resulting voltammetry wa
s compared to that of dimeric model compounds and electrochemically deposit
ed poly(o-phenetidine) films on Au electrodes, RAIRS and electrochemical da
ta reveal that electrochemical oxidation of AnC6SH and AnC7SH monolayers on
Au results in the formation of surface-confined poly(aniline) as well as a
niline dimers and hydrolyzed aniline dimers.