T. Shinmura et al., Isothermal solidification behavior during the transient liquid phase bonding process of nickel using binary filler metals, MATER T JIM, 42(2), 2001, pp. 292-297
Transient liquid phase (TLP) bonding process of Ni using Ni-11.0 mass%P bin
ary filler metal was simulated by using a mathematical model based on diffu
sion analysis. In the model, diffusion-controlled transformation was assume
d, and the base metal dissolution in the early stage and the subsequent iso
thermal solidification stage of the TLP bonding process were simulated. The
calculated width of me eutectic structure at the bonding region agreed wel
l with the experimental result and showed the validity of the model, in ord
er to obtain the condition to reduce isothermal solidification time, the ef
fect of factors, such as the width of filler metal, diffusivity of solute e
lement in Ni and partition coefficient of element, were investigated by num
erical simulation. The simulation showed that isothermal solidification lim
e remarkably decreases with increasing partition coefficient of solute elem
ent. In order to confirm the numerical prediction, the TLP bonding experime
nt of Nj using Cu filler metal was carried out (the partition coefficient o
f Cu in Ni is close to unity). The experimental result showed that Cu fille
r metal remarkably shortened the isothermal solidification time and showed
the validity of the prediction.