The characteristics of opals with various colours found in rhyolitic volcan
ic rocks from Simav district (west Anatolia, Turkey) were studied by optica
l, X-ray, thermoanalytical and infrared-absorption methods and scanning ele
ctron microscope-energy dispersive X-ray spectrometer. Four different silic
a polymorphs were distinguished. These are massy opal-CT found as nodules,
prismatic trydimite crystals found in geodes with opal-CT, fibrous opal-C a
s spherulites and authigenic microcrystalline quartz found in the voids, fr
actures and matrix of the rhyolites. Opal-CT which is known as "Simav's fir
e opal" has high water content related to its fractured and disordered micr
ostructure. The colour variation of massy opal-CT is due to its structural
states and changes in its composition. Simav's opals were precipitated from
saturated siliceous solutions under low temperatures.