Electronic communication in a novel five-step redox system

Authors
Ding, L Ma, KB de Biani, FF Bolte, M Zanello, P Wagner, M
Citation
L. Ding et al., Electronic communication in a novel five-step redox system, ORGANOMETAL, 20(6), 2001, pp. 1041-1043
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
6
Year of publication
2001
Pages
1041 - 1043
Database
ISI
SICI code
0276-7333(20010319)20:6<1041:ECIANF>2.0.ZU;2-4
Abstract
The ansa-ferrocene complex [1,1'-fc(Bbipy)(2)O]-(PF6)(2) {[5](PF6)(2); fc = (n(5)-C5H4)(2)Fe} has been synthesized and structurally characterized. Ele ctronic communication between the true 2,2'-bipyridylboronium substituents was observed suggesting the reduced forms [5](+) and [5](-) to be partially delocalized redox intermediates.