Structure of a benzylcalcium diastereomer: An initiator for the anionic polymerization of styrene

Authors
Harder, S Feil, F Weeber, A
Citation
S. Harder et al., Structure of a benzylcalcium diastereomer: An initiator for the anionic polymerization of styrene, ORGANOMETAL, 20(6), 2001, pp. 1044-1046
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
6
Year of publication
2001
Pages
1044 - 1046
Database
ISI
SICI code
0276-7333(20010319)20:6<1044:SOABDA>2.0.ZU;2-I
Abstract
A new dibenzylcalcium compound with chiral anionic centers has been prepare d and was structurally characterized. The compound, which shows slow invers ion of the chiral carbanions, is an active,initiator for the living polymer ization of styrene.