Two-dimensional diffraction from enantiopure and racemic monolayers of [Ru(bpy)(3)](2+) intercalated into synthetic fluorohectorite

Authors
Breu, J Stoll, A Lange, KG Probst, T
Citation
J. Breu et al., Two-dimensional diffraction from enantiopure and racemic monolayers of [Ru(bpy)(3)](2+) intercalated into synthetic fluorohectorite, PHYS CHEM P, 3(7), 2001, pp. 1232-1235
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
3
Issue
7
Year of publication
2001
Pages
1232 - 1235
Database
ISI
SICI code
1463-9076(2001)3:7<1232:TDFEAR>2.0.ZU;2-8
Abstract
While for intercalation compounds of natural smectites 2D long range order of the interlamellar space was never observed, in-plane order can be detect ed using a homogeneously charged synthetic fluorohectorite as host material . With these intercalates distinct 2D structures for enantiopure and racemi c [Ru(bpy)(3)](2+)-interlayers, as previously predicted by atomistic simula tions, can now be proven experimentally.