The long-standing puzzle of why capillary lengths measured in cellular nema
tic-isotropic interfaces are much longer than the value of 0.05 Angstrom pr
edicted by Mullins-Sekerka theory has been solved. The resolution of the pa
radox is that in confined systems the substrate-nematic anchoring energy co
ntributes to the capillary length which is greatly increased by selective a
dsorption of ions on the Substrate.