Within the context of optimizing blast furnace and liquid steel processes t
he timeliness of the slag analysis deserves special attention. In addition
to analytical precision, the cost and time required for the analysis play c
entral roles. The laser-induced breakdown spectroscopy provides all require
ments necessary for quick analysis of both metallic and oxidic materials as
an important element of production control. To enable the direct analysis
of slags the sampling method of liquid slag had first to be modified in ord
er to meet the requirements of this new analysis technique. Special probes
were used for taking the slag samples. The optimization of the filling and
cooling conditions led to samples with smooth surfaces and only very few st
ress cracks. The samples were suitable for immediate analysis by laser-indu
ced breakdown spectroscopy (LIBS). This method requires considerably less t
ime for the analysis than XRF spectroscopy. Due to the lack of reference ma
terials, the new analytical equipment is calibrated based on the results ob
tained from parallel XRF analyses of solidified vitreous slag samples.
The comparison of the LIBS results with the results obtained by XRF analysi
s has shown good agreement. However, precision is poorer. But as long as th
e achievable precision is within the required tolerance limits the LIES is
a suitable analytical means for process control purposes. The different sla
g amounts and viscosities in liquid steel processes as well as specific on-
site situations (converter, ladle) pose additional problems for successful
slag sampling. Currently, yield rates of 80 % are achieved. The target is >
98%.