Palladium-tetraphosphine catalysed allylic substitution in water

Authors
Feuerstein, M Laurenti, D Doucet, H Santelli, M
Citation
M. Feuerstein et al., Palladium-tetraphosphine catalysed allylic substitution in water, TETRAHEDR L, 42(12), 2001, pp. 2313-2315
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
12
Year of publication
2001
Pages
2313 - 2315
Database
ISI
SICI code
0040-4039(20010318)42:12<2313:PCASIW>2.0.ZU;2-I
Abstract
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl (C3H5)](2) system catalyses allylic amination in water with very high subst rate/catalyst ratio in good yields. A turnover number of 980 000 can be obt ained for the addition of dipropylamine to allyl acetate in the presence of this catalyst. (C) 2001 Elsevier Science Ltd. All rights reserved.