A new intramolecular migration of the imino group of O-arylketoximes to the aryl group under the Beckmann condition

Authors
Kikugawa, Y Tsuji, C Miyazawa, E Sakamoto, T
Citation
Y. Kikugawa et al., A new intramolecular migration of the imino group of O-arylketoximes to the aryl group under the Beckmann condition, TETRAHEDR L, 42(12), 2001, pp. 2337-2339
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
12
Year of publication
2001
Pages
2337 - 2339
Database
ISI
SICI code
0040-4039(20010318)42:12<2337:ANIMOT>2.0.ZU;2-3
Abstract
ZrCl4-mediated decomposition of O-arylketoximes in benzene leads to regiose lective intramolecular migration of the imino group from the oxygen to the ortho position of the aryl group via electron-deficient nitrogen intermedia tes. (C) 2001 Elsevier Science Ltd. All rights reserved.