Jp. Bouillon et al., Fluorinated ketene dithioacetals. Part 7: New beta-halo perfluorodithiocrotonic acid esters from perfluoroketene dithioacetals, TETRAHEDR L, 42(11), 2001, pp. 2133-2135
Esters of beta -bromo or beta -chloro perfluorodithiocrotonic acid were pre
pared from corresponding ketenedithioacetal with anhydrous magnesium halide
s. These new polyfluorinated dithiocarboxylates are good dienophiles reacti
ng selectively via the C=S bond. (C) 2001 Elsevier Science Ltd. All rights
reserved.