Citation
Yq. Tu et al., Diastereo-recognizable reaction between Cr(VI) reagents and tertiary alpha-hydroxy epoxide, TETRAHEDR L, 42(11), 2001, pp. 2141-2144
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039
→ ACNP
Volume
42
Issue
11
Year of publication
2001
Pages
2141 - 2144
Database
ISI
SICI code
0040-4039(20010311)42:11<2141:DRBCRA>2.0.ZU;2-Y
Abstract
Chromium(VI) reagents containing pyridine derivatives were found to be able
to oxidize diastereo-recognizably tertiary cc-hydroxy epoxides to form car
bonyl compounds. The correlation of structure-selectivity of this reaction
was discussed, and the diastereo-recognizability proved to be dependent lar
gely upon the substitution patterns of the pyridine moiety. (C) 2001 Elsevi
er Science Ltd. All rights reserved.