Growing evidence suggests that the first generation of stars may have been
quite massive (similar to 100-300 M-.). If they retain their high mass unti
l death, such stars will, after about 3 Myr, make pair-instability supernov
ae. Models for these explosions have been discussed in the literature for f
our decades, but very few included the effects of rotation and none employe
d a realistic model for neutrino trapping and transport. Both turn out to b
e very important, especially for those stars whose cores collapse into blac
k holes (helium cores above about 133 M-.). We consider the complete evolut
ion of two zero-metallicity stars of 250 and 300 M-.. Despite their large m
asses, we argue that the low metallicities of these stars imply negligible
mass loss. Evolving the stars with no mass loss, but including angular mome
ntum transport and rotationally induced mixing, the two stars produce heliu
m cores of 130 and 180 M-.. Products of central helium burning (e.g., prima
ry nitrogen) are mixed into the hydrogen envelope with dramatic effects on
the radius, especially in the case of the 300 M-. model. Explosive oxygen a
nd silicon burning cause the 130 helium core (250 M-. star) to explode, but
explosive burning is unable to drive an explosion in the 180 M-. helium co
re, and it collapses to a black hole. For this star, the calculated angular
momentum in the presupernova model is sufficient to delay black hole forma
tion, and the star initially forms an similar to 50 M-. 1000 km core within
which neutrinos are trapped. The calculated growth time for secular rotati
onal instabilities in this core is shorter than the black hole formation ti
me, and they may develop. If so, the estimated gravitational wave energy an
d wave amplitude are E-GW approximate to 10(-3) M-. c(2) and h(+) approxima
te to 10(-21)/d(Gpc), but these estimates are very rough and depend sensiti
vely on the nonlinear nature of the instabilities. After the black hole for
ms, accretion continues through a disk. The mass of the disk depends on the
adopted viscosity but may be quite large, up to 30 M-. when the black hole
mass is 140 M-.. The accretion rate through the disk can be as large as 1-
10 M-. s(-1). Although the disk is far too large and cool to transport ener
gy efficiently to the rotational axis by neutrino annihilation, it has ampl
e potential energy to produce a 10(54) erg jet driven by magnetic fields. T
he interaction of this jet with surrounding circumstellar gas may produce a
n energetic gamma-ray transient, but given the probable redshift and the co
nsequent timescale and spectrum, this model may have difficulty explaining
typical gamma-ray bursts.