Absolute configuration of 2,6-di-O-alkylgalactose obtained from peralkylated red algal polysaccharides

Citation
Mi. Errea et al., Absolute configuration of 2,6-di-O-alkylgalactose obtained from peralkylated red algal polysaccharides, BOTAN MARIN, 44(2), 2001, pp. 133-138
Citations number
21
Categorie Soggetti
Aquatic Sciences
Journal title
BOTANICA MARINA
ISSN journal
00068055 → ACNP
Volume
44
Issue
2
Year of publication
2001
Pages
133 - 138
Database
ISI
SICI code
0006-8055(200103)44:2<133:ACO2OF>2.0.ZU;2-Z
Abstract
A method to determine the proportion of both enantiomers of 2,6-di-O-alkylg alactose in a permethylated/perethylated polysaccharide is described. It in volves conversion of the monosaccharides, obtained by hydrolysis of the sam ple, to the corresponding diastereomeric acetylated 1-deoxy-1-(1-phenylethy lamino)alditols, followed by gas chromatographic analysis. This procedure h as been applied to a polysaccharide isolated from Pteracladiella capillacea .