The first total synthesis of grandinal, a new phloroglucinol derivative isolated from Eucalyptus grandis

Authors
Matsumoto, T Singh, IP Etoh, H Tanaka, H
Citation
T. Matsumoto et al., The first total synthesis of grandinal, a new phloroglucinol derivative isolated from Eucalyptus grandis, CHEM LETT, (3), 2001, pp. 210-211
Citations number
5
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
3
Year of publication
2001
Pages
210 - 211
Database
ISI
SICI code
0366-7022(20010305):3<210:TFTSOG>2.0.ZU;2-3
Abstract
The first total synthesis of grandinal (1) is accomplished by biomimetic cy cloaddition of the jensenone derivative (2) and the o-quinone methide (3) g enerated by oxidation of grandinol (4).