Combined diffusion model for the sorption of cadmium, copper, and zinc ions onto bone char

The ability of bone char to remove three single-component metals (namely, c admium, copper and zinc) from aqueous solutions has been studied. Equilibri um isotherms have been measured and analyzed using a Langmuir isotherm mode l. A series of batch contact time experiments were performed to study the e ffect of sorbent mass and initial metal ion concentration for the three sys tems. A new film-pore diffusion model has been applied to the batch contact time results, and good correlation is obtained between theoretical predict ions and experimental data. A further extension to the new model was made t o include a surface diffusion term. The agreement between theoretical resul ts and experimental data improved as the sum of the squares of the errors ( SSE) improved by around 20% for cadmium and zinc but by 50% for copper. The refore, the sorptions of cadmium and zinc ions onto bone char are primarily film-pore diffusion controlled, but for the copper system film-pore-surfac e diffusion must be considered.