Stereoselective synthesis of hexacoordinated mononuclear cyclometalated rhodium(III) complexes - Transfer of chirality from the metal center to the ligand

Authors
Ghizdavu, L von Zelewsky, A Stoeckli-Evans, H
Citation
L. Ghizdavu et al., Stereoselective synthesis of hexacoordinated mononuclear cyclometalated rhodium(III) complexes - Transfer of chirality from the metal center to the ligand, EUR J INORG, (4), 2001, pp. 993-1003
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
4
Year of publication
2001
Pages
993 - 1003
Database
ISI
SICI code
1434-1948(200104):4<993:SSOHMC>2.0.ZU;2-X
Abstract
The cleavage of Delta Delta [Rh(th4,5ppy)(2)(mu -Cl)](2) th4,5ppy is enanti ometrically by 5 different diimines and 11 diamines yields monomeric cation s Delta [Rh(th4,5ppy)(2)(N boolean ANDN)](+). In all cases, the cleavage re action preserves the original Delta configuration at the metal center, When N boolean ANDN is a chiral or a prochiral ligand.