A two-dimensional spin model of Al/Si order in feldspars: visualization ofshort-range and long-range order

Ordering schemes analogous to the Al,Si ordering in albite and anorthite ar e simulated using a two-dimensional spin model. Equilibrium calculations ar e performed using the square approximation of the cluster variation method. A stochastic algorithm is developed to visualize ordering patterns and dom ain textures of typical Al,Si configurations with short- and long-range ord er. At the rather low Al/Si ratio of albite a high degree of short-range order (SRO) is expected as a consequence of strong interaction within first-neigh bour Al,Si pairs. At a higher Al/Si ratio of anorthite long-range order (LR O) of anorthite-type appears to be a better alternative to the SRO. The SRO /LRO transition occurs due to the destabilization of anti-phase boundaries between short-range ordered domains. LRO of albite-type is stabilized mainl y by the interaction within second-neighbour Al,Si pairs, which is less str ong in comparison to the first-neighbor interaction.