Synthesis of a new system containing a pyramidalized double bond: Lack of reactivity of a strongly protected pyramidalized double bond

Authors
Saracoglu, N Balci, M
Citation
N. Saracoglu et M. Balci, Synthesis of a new system containing a pyramidalized double bond: Lack of reactivity of a strongly protected pyramidalized double bond, HELV CHIM A, 84(3), 2001, pp. 707-714
Citations number
25
Categorie Soggetti
Chemistry & Analysis",Chemistry
Journal title
HELVETICA CHIMICA ACTA
ISSN journal
0018019X → ACNP
Volume
84
Issue
3
Year of publication
2001
Pages
707 - 714
Database
ISI
SICI code
0018-019X(2001)84:3<707:SOANSC>2.0.ZU;2-J
Abstract
The chemical reactivity of syn-3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemica l reactions. To determine the reactivity of this central double bond. we sy nthesized syn- and anti-7 and recorded their photoelectron spectra. Low fir st-ionization potentials of syn- and anti-7 (7.6 eV) dearly indicated that these compounds should be highly reactive.