SYNTHESIS OF NOVEL RUTHENIUM COMPLEXES CONTAINING BIDENTATE IMIDAZOLE-BASED LIGANDS

Authors
ELGAFI S FIELD LD MESSERLE BA HAMBLEY TW TURNER P
Citation
S. Elgafi et al., SYNTHESIS OF NOVEL RUTHENIUM COMPLEXES CONTAINING BIDENTATE IMIDAZOLE-BASED LIGANDS, Journal of the Chemical Society. Dalton transactions, (13), 1997, pp. 2341-2345
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
13
Year of publication
1997
Pages
2341 - 2345
Database
ISI
SICI code
0300-9246(1997):13<2341:SONRCC>2.0.ZU;2-Z
Abstract
Ruthenium(II) complexes containing the bidentate imidazole-based ligan ds (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1 , [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthe sized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluen e. The complexes were characterised by NMR spectroscopy and the crysta l structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.