S-CENTER-DOT-CENTER-DOT-CENTER-DOT-S CONTACT-ASSEMBLED SILVER(I) COMPLEXES OF 4,5-ETHYLENEDITHIO-1,3-DITHIOLE-2-THIONE HAVING UNIQUE SUPRAMOLECULAR NETWORKS

Authors
DAI J KURODASOWA T MUNAKATA M MAEKAWA M SUENAGA Y OHNO Y
Citation
J. Dai et al., S-CENTER-DOT-CENTER-DOT-CENTER-DOT-S CONTACT-ASSEMBLED SILVER(I) COMPLEXES OF 4,5-ETHYLENEDITHIO-1,3-DITHIOLE-2-THIONE HAVING UNIQUE SUPRAMOLECULAR NETWORKS, Journal of the Chemical Society. Dalton transactions, (13), 1997, pp. 2363-2368
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
13
Year of publication
1997
Pages
2363 - 2368
Database
ISI
SICI code
0300-9246(1997):13<2363:SCSC>2.0.ZU;2-3
Abstract
Two silver(I) complexes of 4,5-ethylenedithio-1,3-dithiole-2-thione (C 5H4S5), [{Ag(C5H4S5)(3)}ClO4 . CH3CN](2) and [Ag(C5H4S5)CF3SO3](infini ty) have been synthesized and characterized crystallographically. They have unique dimeric and two-dimensional structures respectively and a re assembled by S ... S contacts. The finding of the shortest S ... S contacts (3.284 and 3.262 Angstrom) in these complexes indicated that the co-ordination linkage in metal complexes containing these types of sulfur donor compounds could be expected to control the intra- or int er-molecular interactions. The co-ordination mode of the C5H4S5 ligand has also been discussed.