The positive oxide charge (Q(ox)) and the concentration of nonradiative rec
ombination defects (N-it) at a thin anodic oxide/p-Si interface are probed
in situ by pulsed photovoltage and photoluminescence techniques during elec
tron injection. Q(ox) and N-it decreased strongly due to electron injection
. The observed effect is suggested to be inverse to the negative-bias-tempe
rature instability. Defect reactions at the anodic oxide/p-Si interface are
discussed. (C) 2001 American Institute of Physics.