Thermodynamic properties of binary mixtures containing hydrofluoroether

Excess molar enthalpy and excess molar volume at T = 298.15 K are reported for binary mixtures of (nonafluorobutylmethylelher + butylmethylether, or n onane, or heptane, or pentane, or 1-propanol, or 2-propoxyethanol). Excess molar enthalpies of the mixture of (nonafluorobutylmethylether + 1-pentanol ) also are reported at T = 298.15 K. The results of excess molar enthalpy a re endothermic and the results of excess molar volume are positive in the w hole concentration for all the mixtures. The phase separation is found in t he range of 0.15 < x < 0.92 for the 1-pentanol system. The results are expl ained by means of the destruction of the dipolar interactions and hydrogen bonds in the component liquids, the difference of the dispersion interactio n, and the formation of the intermolecular hydrogen bonds between unlike mo lecules. (C) 2001 Academic Press.