Ultrahigh-resolution photoemission study of CePd3: absence of Kondo insulator gap

Citation
S. Souma et al., Ultrahigh-resolution photoemission study of CePd3: absence of Kondo insulator gap, J ELEC SPEC, 114, 2001, pp. 735-740
Citations number
21
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
ISSN journal
03682048 → ACNP
Volume
114
Year of publication
2001
Pages
735 - 740
Database
ISI
SICI code
0368-2048(200103)114:<735:UPSOCA>2.0.ZU;2-X
Abstract
We have performed ultrahigh-resolution (DeltaE=8 meV) photoemission spectro scopy to examine the possibility of CePd3 being a 'Kondo insulator' as sugg ested by a recent optical measurement [Phys. Rev. B 53 (1996) R2948]. We fo und that the photoemission spectrum of CePd3 does not show any indication o f (pseudo) gap at E-F, differing from the well-established tempsrature-depe ndent (pseudo) Sap in Kondo insulators. The Ce 4f spectrum clearly shows th e 'Kondo resonance peak' at E-F, indicating the intrinsic metallic nature o f CePd3. These results strongly suggest that CePd3 is not a Kondo insulator but a conventional Kondo metal as suggested by thermodynamic measurements. (C) 2001 Elsevier Science B.V. All rights reserved.