Pronounced temperature effects in angular resolved ultraviolet photoelectro
n spectroscopy from the (001) surface of the ternary heavy fermion compound
CeNi2Ge2 are presented. The measurements were performed on atomically clea
n and well-ordered thin films grown on a W(110) substrate. A strongly enhan
ced intensity at the Fermi edge (E-F) is observed at low-temperatures if th
e spectra are excited by means of HeI light (hv=21.2 eV). In addition, the
work function is dramatically increased with temperature, exhibiting an unu
sually high positive temperature coefficient of about 0.65 meV/K. The obser
ved temperature dependency suggests a strong redistribution of the states n
ear the Fermi-energy with increasing temperature. A simple model will be gi
ven that correlates the observed intensity changes at E-F with the change o
f the work function. (C) 2001 Elsevier Science B.V. All rights reserved.