An infrared spectroscopic study on the Hofmann- and en-T-d-type clathrates: Mn(NH3)(2)Zn(CN)(4).2benzene and Mn(ethylenediamine)Zn(CN)(4).2benzene

Authors
Kantarci, Z Bayrak, C Kasap, E
Citation
Z. Kantarci et al., An infrared spectroscopic study on the Hofmann- and en-T-d-type clathrates: Mn(NH3)(2)Zn(CN)(4).2benzene and Mn(ethylenediamine)Zn(CN)(4).2benzene, J INCL P MA, 39(1-2), 2001, pp. 103-108
Citations number
25
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
ISSN journal
13883127 → ACNP
Volume
39
Issue
1-2
Year of publication
2001
Pages
103 - 108
Database
ISI
SICI code
1388-3127(200102)39:1-2<103:AISSOT>2.0.ZU;2-I
Abstract
Infrared spectra of Mn(NH3)(2)Zn(CN)(4). 2C(6)H(6) and Mn(ethylenediamine)Z n(CN)(4). 2C(6)H(6) are reported. The spectral data suggest that these comp ounds are similar in structure to Hofmann-T-d-type and the en-T-d-type clat hrates, respectively. There is good evidence for H-bonding from ammonia N-H to benzene as a pi to sigma H-bond.