An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl)

Citation
M. Senyel et al., An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl), J INCL P MA, 39(1-2), 2001, pp. 175-180
Citations number
15
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
ISSN journal
13883127 → ACNP
Volume
39
Issue
1-2
Year of publication
2001
Pages
175 - 180
Database
ISI
SICI code
1388-3127(200102)39:1-2<175:AISSOT>2.0.ZU;2-W
Abstract
Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminodod ecane) Ni(CN)(4).G (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diam inododecane molecules in the host lattice permit the inclusion of bulky gue st molecules. The spectral features suggest that these compounds are simila r in structure to the other Hofmann-diam-type clathrates.