An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl)
M. Senyel et al., An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl), J INCL P MA, 39(1-2), 2001, pp. 175-180
Citations number
15
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminodod
ecane) Ni(CN)(4).G (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene,
phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diam
inododecane molecules in the host lattice permit the inclusion of bulky gue
st molecules. The spectral features suggest that these compounds are simila
r in structure to the other Hofmann-diam-type clathrates.