PHOTOCHEMISTRY OF NONCONJUGATED BICHROMOPHORIC SYSTEMS .3. SYNTHESIS AND PHOTOREACTION OF POLY(ETHYLENE GLYCOL) BISCOUMARINYLOXYACETATES

Authors
WANG YM DU DM MENG JB ZHOU XZ WANG L
Citation
Ym. Wang et al., PHOTOCHEMISTRY OF NONCONJUGATED BICHROMOPHORIC SYSTEMS .3. SYNTHESIS AND PHOTOREACTION OF POLY(ETHYLENE GLYCOL) BISCOUMARINYLOXYACETATES, Chinese journal of chemistry, 15(2), 1997, pp. 169-173
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chinese journal of chemistry → ACNP
ISSN journal
1001604X
Volume
15
Issue
2
Year of publication
1997
Pages
169 - 173
Database
ISI
SICI code
1001-604X(1997)15:2<169:PONBS.>2.0.ZU;2-K
Abstract
A series of poly(ethylene glycol) biscoumarinyloxyacetates have been s ynthesized and their intramolecular photochemical cyclodimerizations h ave been studied. It was found that only syn-HT configuration products were obtained when these bisesters were directly irradiated in chloro form, and the yields of the products decreased with the increase of th e chain length. This photocyclization reaction is a convenient and eff ective method to synthesize macrocyclic compounds.