Ni. Golovina et al., Experimental study of structure-energy changes in molecules and crystals of 2,2-dinitropropane-1,3-diol caused by temperature variations, J SOL ST CH, 157(2), 2001, pp. 296-308
Crystals of 2,2-dinitropropane-1,3-diol were prepared and grown at differen
t temperatures. An X-ray analysis was used to study the structure of three
phases (1, 2 and 3) of the 2,2-dinitropropane-1,3-diol crystals. The calori
metric study of the crystals temperature behavior (1) showed the presence o
f two phase transitions in the regions of T = 309 K and T = 340 K, as well
as crystals (2) with a phase transition at T = 340 K, Observations in a hot
stage with the optical microscope phase transitions for separate crystals
were made. X-ray diffraction studies of polycrystalline samples (1) for tem
peratures increasing up to the temperatures of phase transitions I and II d
emonstrated that phase transition I is followed by conversion of crystals 1
into 2, and transition II is connected with conversion of crystals 2 into
a disordered body-centered structure. The temperature behavior of the bands
of symmetric N-O stretching vibrations of nitro groups and stretching vibr
ations of O-H groups was studied by IR spectroscopy. The temperature depend
ence of hydrogen bonds redistribution and nitro group reorientational dynam
ics was examined. Data on the structure-dynamic rearrangement in the crysta
l lattice of the examined compound were obtained by the NMR pulse method in
the solid phase using relaxational free induction decay of protons. The ki
netic parameters of the process were obtained. (C) 2001 Academic Press.