The low-pressure CVD synthesis of diamond enables the growth of pure diamon
d coatings from the gas phase. For this process, in all cases, a substrate
is needed on which diamond can nucleate and grow. Besides the diamond depos
ition parameters (e.g., pressure, temperature, gas flow), which directly in
fluence the diamond nucleation and growth, the nature of the substrates and
their interactions with the reaction gases and the diamond are important f
actors to consider in order to achieve good deposition results. The main su
bstrate interactions and their influences on diamond deposition are summari
zed. Additionally a short overview of the substrate pre-treatment process a
nd diamond epitaxy is given.