We propose that in QCD with dynamical quarks, colour deconfinement occurs w
hen an external field induced by the chiral condensate strongly aligns the
Polyakov loop. This effect sets in at the chiral symmetry restoration tempe
rature Tx and thus makes deconfinement and chiral symmetry restoration coin
cide. The predicted singular behavior of Polyakov loop susceptibilities at
T-chi is shown to be supported by finite temperature lattice calculations.