The nonlinear, exponential characteristic (EC) method is extended to unstru
ctured meshes of tetrahedral cells in three-dimensional Cartesian coordinat
es. The split-cell approach developed for the linear characteristic (LC) me
thod on such meshes is used. Exponential distributions of the source within
a cell and of the inflow flux on upstream faces of the cell are assumed. T
he coefficients of these distributions are determined by nonlinear root sol
ving so as to match the zeroth and first moments of the source or entering
flux Good conditioning is achieved by casting the formulas for the moments
of the source, inflow flux, and solution flux as stems of positive function
s and by using accurate and robust algorithms for evaluation of those funct
ions. Various test problems are used to compare the performance of the EC a
nd LC methods. The EC method is somewhat less accurate than the LC method i
n regions of net out leakage brit is strictly positive and retains good acc
uracy with optically thick cells, as in shielding problems, unlike the LC m
ethod. The computational cost per cell is greater for the EC method bur the
use of substantially coarser meshes can make the EC method less expensive
in total cost. The EC method, unlike the LC method, may fail if negative cr
oss sections or angular quadrature weights are used. It is concluded that t
he EC and LC methods should be practical, reliable, and complimentary schem
es for these meshes.