Citation
Am. Gaber et al., Thermolysis and photolysis of aryl thiocarbamate derivatives, PHOSPHOR SU, 166, 2000, pp. 243-251
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507
→ ACNP
Volume
166
Year of publication
2000
Pages
243 - 251
Database
ISI
SICI code
1042-6507(2000)166:<243:TAPOAT>2.0.ZU;2-J
Abstract
Thermolysis of N-phenyl-O-phenylthiocarbamate (POPTC), N-phenyl-O-benzylthi
ocarbamate (POBTC), and N-phenyl-S-phenylthiocarbamate (PSPN3) by reflux fo
r 15 hr at 220-230 degreesC affords degradation products assumed to be form
ed by homolysis at different sites furnishing free radicals that undergo su
bsequent reactions involving H-abstraction, dimerization, disproportionatio
n and/or fragmentation to give the identified products. Similar results are
also obtained on photolysis of such thiocarbamate derivatives.