S. Takeoka et al., Photoluminescence from Si nanocrystals embedded in SiO2 matrices in a weakconfinement regime, PHYS ST S-B, 224(1), 2001, pp. 229-232
We have studied photoluminescence (PL) from surface-oxidized Si nanocrystal
s (nc-Si) as a function of the size (4.2-9.0 nm in diameter). As the size d
ecreased. a high-energy shift of the PL peak from the vicinity of the bulk
band gap to the visible region was observed for the first time. This PL shi
ft was accompanied by the shortening of the PL lifetime and the increase in
the exchange splitting energy of excitons.