We report a combined theoretical and experimental investigation of quantum
confinement effects on the E-1 interband structures in the optical spectra
of Ge quantum dots. The experimental average radius goes from approximate t
o 12 to approximate to 60 Angstrom. A blueshift of the E-1 absorption peak
(up to 0.1 eV) and a strong reduction in the oscillator strength, are measu
red effects of the quantum confinement. The theoretical analysis is perform
ed for nanocrystals up to 15 Angstrom through a semi-empirical tight-bindin
g approach. We overcome the single-particle scheme including, in a perturba
tive approach. the Coulomb electron-hole interaction which induces a red-sh
ift of the E-1 peak with respect to the one-electron calculation.