Synthesis and characteristics of functionally substituted diacetylene peroxides

Authors
Dikusar, EA Yuvchenko, AP Zvereva, TD Zhukovskaya, NA Moiseichuk, KL
Citation
Ea. Dikusar et al., Synthesis and characteristics of functionally substituted diacetylene peroxides, RUSS J ORG, 36(8), 2000, pp. 1105-1109
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
36
Issue
8
Year of publication
2000
Pages
1105 - 1109
Database
ISI
SICI code
1070-4280(200008)36:8<1105:SACOFS>2.0.ZU;2-8
Abstract
By treating with 3-tert-alkylperoxy-4-bromo-3-methylbut-1-ynes 1-hexyne, pr opargyl alcohol, propiolic acid, m- and p-ethynylbenzoic acids under condit ions of Khodkevich-Kadio reaction the corresponding functionally substitute d diacetylene peroxides were synthesized. The reaction of peroxy-alcohols w ith Ac2O afforded peroxy group containing esters. The relative thermal stab ility of the peroxides obtained was evaluated by means of derivatography.