Novel chiral phosphines derived from limonene: the synthesis and structureof 4,8-dimethyl-2-phosphabicyclo[3.3.1]nonane

Authors
Robertson, A Bradaric, C Frampton, CS McNulty, J Capretta, A
Citation
A. Robertson et al., Novel chiral phosphines derived from limonene: the synthesis and structureof 4,8-dimethyl-2-phosphabicyclo[3.3.1]nonane, TETRAHEDR L, 42(14), 2001, pp. 2609-2612
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
14
Year of publication
2001
Pages
2609 - 2612
Database
ISI
SICI code
0040-4039(20010402)42:14<2609:NCPDFL>2.0.ZU;2-G
Abstract
The radical addition of PH3 to limonene results in the formation of 4,8-dim ethyl-2-phosphabicyclo[3.3.1]nonane, which has been characterized by X-ray crystallographic analyses of its oxidation products, 2-(4-methylcyclohexyl) propylphosphonic acid and 4.8-dimethyl-2-phosphabicyclo[3.3.1]nonan-2-ol-ox ide. (C) 2001 Elsevier Science Ltd. All rights reserved.