C. Bernal et al., Differences in thermal decomposition of Ag(I), Mn(II), Fe(II) and Fe(III) complexes of cyclic dithiocarbamates, THERMOC ACT, 370(1-2), 2001, pp. 49-55
The thermal decomposition of pyrrolidinedithiocarbamate (Pyr) and piperidin
edithiocarbamate (Pip) complexes of Ag(I), Mn(II), Fe(II) and Fe(III) have
been investigated by thermogravimetry and differential scanning calorimetry
. The decomposition intermediates and final products were identified from t
heir X-ray diffraction patterns. Changes in their IR spectra were correlate
d with their thermogravimetric profiles. The hydrated compounds decomposed
without loss of water and oxides were detected as the final decomposition p
roducts even in nitrogen atmosphere. (C) 2001 Elsevier Science B.V. All rig
hts reserved.