Differences in thermal decomposition of Ag(I), Mn(II), Fe(II) and Fe(III) complexes of cyclic dithiocarbamates

Citation
C. Bernal et al., Differences in thermal decomposition of Ag(I), Mn(II), Fe(II) and Fe(III) complexes of cyclic dithiocarbamates, THERMOC ACT, 370(1-2), 2001, pp. 49-55
Citations number
24
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
THERMOCHIMICA ACTA
ISSN journal
00406031 → ACNP
Volume
370
Issue
1-2
Year of publication
2001
Pages
49 - 55
Database
ISI
SICI code
0040-6031(20010404)370:1-2<49:DITDOA>2.0.ZU;2-P
Abstract
The thermal decomposition of pyrrolidinedithiocarbamate (Pyr) and piperidin edithiocarbamate (Pip) complexes of Ag(I), Mn(II), Fe(II) and Fe(III) have been investigated by thermogravimetry and differential scanning calorimetry . The decomposition intermediates and final products were identified from t heir X-ray diffraction patterns. Changes in their IR spectra were correlate d with their thermogravimetric profiles. The hydrated compounds decomposed without loss of water and oxides were detected as the final decomposition p roducts even in nitrogen atmosphere. (C) 2001 Elsevier Science B.V. All rig hts reserved.