The thermal behaviour of nickel, copper and zinc complexes with the Schiffbases cis- and trans-N,N '-bis(salicylidene)-1,2-ciclohexadiamine (Salcn)

Authors
Cavalheiro, ETG Lemos, FCD Schpector, JZ Dockal, ER
Citation
Etg. Cavalheiro et al., The thermal behaviour of nickel, copper and zinc complexes with the Schiffbases cis- and trans-N,N '-bis(salicylidene)-1,2-ciclohexadiamine (Salcn), THERMOC ACT, 370(1-2), 2001, pp. 129-133
Citations number
15
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
THERMOCHIMICA ACTA
ISSN journal
00406031 → ACNP
Volume
370
Issue
1-2
Year of publication
2001
Pages
129 - 133
Database
ISI
SICI code
0040-6031(20010404)370:1-2<129:TTBONC>2.0.ZU;2-Q
Abstract
The Schiff base complexes were prepared and characterised by UV, IR and NMR (H-1 and C-13) spectroscopy, elemental analysis and X-ray powder diffracto metry. Free ligands and some new complexes were submitted to thermal analys is (TG and DSC) under dynamic air atmosphere. The differences in the decomp osition profiles were related to the structure of isomers and decomposition intermediates were characterised according to their X-ray diffraction patt ern. (C) 2001 Elsevier Science B.V. All rights reserved.