A series of dialdehyde cellulose samples with varied aldehyde content were
prepared, and they were further converted to nitrogen-containing derivative
s by Schiff base reaction with hydroxylamine or hydrazine. Thermal decompos
ition of these compounds in nitrogen was studied by thermogravimetry/differ
ential thermal analysis (TG/DTA). While the decomposition of unmodified cel
lulose in nitrogen started at about 280 degreesC and rapid weight loss occu
rred at 300-330 degreesC, the introduction of dialdehyde groups to cellulos
e resulted in significant shifts of decomposition to the lower temperature
side. The samples of high degree of substitution showed two-step decomposit
ion at around 220 and 280 degreesC, indicating a basic change in the mode o
f decomposition. The nitrogen-containing derivatives showed changes in ther
mal decomposition similar to that of dialdehyde cellulose, hut the samples
with high degrees of substitution, above similar to 70%, showed an explosiv
e decomposition at 151-162 degreesC. This anomalous phenomenon stems charac
teristic to the chemical structures involving C=N-N or C=N-O groups. (C) 20
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