Kn. Semenenko et al., The Tian-Calvet calorimetry as a method for investigating heterogeneous hydrogenation catalysts based on IMC disperse powders, THERMOC ACT, 369(1-2), 2001, pp. 161-166
The interaction of hydrogen with LaNi3.5Cu1.5 - a catalyst for hydrogenatio
n of organic compounds - was studied in a wide temperature range (308-373 K
) by the Tian-Calvet differential heat-conduction calorimetry. The P-C-T-,
Q-C-T-diagrams and the results of mathematical treatment of the calorimerti
c data are presented. The formation mechanism of active hydrogen solved in
metal matrix is proposed. (C) 2001 Elsevier Science B.V. All rights reserve
d.