Based on the volume averaging method, a macroscopic model is developed for
the upscaling of NAPL transport in a porous medium idealised by a network m
odel. Under the assumption of local mass non-equilibrium, a macroscopic equ
ation involving a dispersion tensor, additional convective terms and a line
ar form for the interfacial mass flux is obtained. The resolution of the tw
o local closure problems obtained allow the determination of the local prop
erties without adjustable parmeters. These problems are solved in a semi-an
alytical, semi-numerical manner on the network. The originality of this wor
k is the association of the upscaling by volume averaging method with the n
etwork approach. The local properties, including the dispersion tensor and
the mass exchange coefficient, can therefore be calculated over a large num
ber of pore-bodies and pore-throats in a computationaly tractable manner, t
hus leading to more significant results. Results are presented for 3D, spat
ially periodic models of porous media.