Effects of precipitation, air temperature, and land use on organic carbon discharges from rhode river watersheds

We studied discharges of organic carbon from eight contiguous small watersh eds on the Atlantic Coastal Plain in Maryland for up to 24 yr. Six of these watersheds were second or third order with mixed-land-use, while two were first order (one completely forested and one highly dominated by cropland). These watersheds have perched aquifers, so all groundwater discharges as w ell as surface runoff were measured at V-notch weirs and flumes, which incl uded volume-integrating flow-proportional samplers. Interannual variations in annual and seasonal precipitation during this study spanned approximatel y the range of 160 yr weather records in the region. Annual total organic c arbon (TOC) area yields from the overall Rhode River watershed varied 8-fol d, correlations with precipitation were highly significant, and a power fun ction regression explained 54% of the variance in annual TOC fluxes. TOC fl uxes were higher from upland forest than mixed land use, and highest from t he cropland-dominated watershed. The fluxes from first order watersheds wer e more variable with precipitation. In the spring, TOC fluxes were highest and most correlated with precipitation, compared to other seasons. Precipit ation volume also explained much of the variance in annual and spring TOC c oncentrations from upland forest and cropland, with concentrations three to five times higher in very wet years than in very dry years. Variation in w inter and summer air temperature was correlated with TOC concentrations fro m forested watersheds, and linear regressions explained 19 to 42% of the va riance in TOC. A regression model was used to construct graphical and tabul ar summaries. Particulate organic carbon and dissolved organic carbon (DOC) concentrations and the ratio of DOC to TOC were highly correlated with wat er discharge for a second order, mixed land use watershed, and power functi on regressions explained 21 to 43% of the variance. For the first order, si ngle-land-use watersheds the ratio of DOC to TOC was also highly correlated with discharge.