Multi-pollutant concentration measurements around a concentrated swine production facility using open-path FTIR spectrometry

Open-path Fourier transform infrared (OP/FTIR) spectrometry was used to mea sure the concentrations of ammonia, methane, and other atmospheric gases ar ound an integrated industrial swine production facility in eastern North Ca rolina. Several single-path measurements were made over an 8-day period fro m 11 to 22 January 1999. Nine different monitoring paths were configured to determine the concentration ranges of ammonia and methane throughout this facility, with an emphasis on isolating the emissions from the farrowing/nu rsery barns, the finishing barns, and the waste lagoon. A series of sequent ial measurements was made on 13 January 1999, to estimate the target gas co ncentrations downwind from each of these sources and at an upwind backgroun d site under similar meteorological conditions. The path-averaged concentra tion (mean +/- standard deviation) of ammonia during these measurements was below the estimated method detection limit of 0.003 ppm at the background site, 0.328 +/- 0.044 ppm between the farrowing/nursery and finishing barns , 2.063 +/- 0.140 ppm perpendicular to the airflow from the exhaust fans of the finishing barns, 0.488 +/- 0.110 ppm along the western berm of the lag oon, and 0.722 +/- 0.659 ppm along the eastern berm of the lagoon. The mean -path-averaged concentration of methane during this same time period was 1. 89 +/- 0.03 ppm at the background site, 2.58 +/- 0.11 ppm between the farro wing/nursery and finishing barns, 2.70 +/- 0.05 ppm perpendicular to the ai rflow from the exhaust fans of the finishing barns, 2.27 +/- 0.06 ppm along the western berm of the lagoon, and 11.02 +/- 9.69 ppm along the eastern b erm of the lagoon as the prevailing westerly winds died down. The concentra tion measurements made along different monitoring paths during this study i ndicate that the confinement barns can be a significant source of ammonia, while the lagoon is a major source of methane. Attempts to apply tracer-bas ed dispersion modeling techniques to the single-path OP/FTIR data to estima te emission rates of ammonia and methane from the different sources present at this facility were met with limited success. (C) 2001 Elsevier Science Ltd. All rights reserved.