Conducting polymers offer a possibility for developing material properties
that are critical to the sensitivity, selectivity and fabrication of potent
iometric solid state gas sensors. The formation of charge transfer complex
between the gaseous species and the semiconducting material results in chem
ical modulation of the work function of the polymer. Methods of primary dop
ing of the conducting polymers that lead to a stable and adjustable value o
f the work function will be discussed using polyaniline as an example.