A new approach to the determination of the number of oxo groups in carbonyl compounds using the chloramine-T oxidative method

Citation
K. Umesha et al., A new approach to the determination of the number of oxo groups in carbonyl compounds using the chloramine-T oxidative method, CHEM ANAL, 46(2), 2001, pp. 269-274
Citations number
7
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
CHEMIA ANALITYCZNA
ISSN journal
00092223 → ACNP
Volume
46
Issue
2
Year of publication
2001
Pages
269 - 274
Database
ISI
SICI code
0009-2223(2001)46:2<269:ANATTD>2.0.ZU;2-J
Abstract
A simple titrimetric method for the determination of the number of the oxo groups in carbonyl compounds via their oximes is described. The method invo lves the oxidative dehydrogenation of the oximes by chloramine-T in water, followed by the iodometric determination of the unreacted chloramine-T.