Neutral and cationic yttrium alkyl complexes with linked 1,4,7-triazacyclononane-amide monoanionic ancillary ligands: synthesis and catalytic ethene polymerisation

Authors
Bambirra, S van Leusen, D Meetsma, A Hessen, B Teuben, JH
Citation
S. Bambirra et al., Neutral and cationic yttrium alkyl complexes with linked 1,4,7-triazacyclononane-amide monoanionic ancillary ligands: synthesis and catalytic ethene polymerisation, CHEM COMMUN, (7), 2001, pp. 637-638
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
7
Year of publication
2001
Pages
637 - 638
Database
ISI
SICI code
1359-7345(2001):7<637:NACYAC>2.0.ZU;2-V
Abstract
Yttrium dialkyl complexes [N,N'-R-2-tacn-N"-(CH2)(2)NBut]Y(CH2SiMe3)(2) (R= Me, Pr-i; tacn=1,4,7-triazacyclononane) were prepared; when activated with [PhNMe2H][B(C6F5)(4)] these complexes form cationic alkyl species that are active ethene polymerisation catalysts.